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Thallium ( Tl )

Material Information

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General Description:  

Thallium was discovered in 1861 by W. Crookes in London, and isolated by C.A. Lamy the following year in Paris.

Thallium is a soft, silvery-grey, reactive metal which is only found as a minor constituent of various minerals (it has an abundance of 0.6 ppm in the earth's crust), from which the metal is obtained by electrolytic reduction in aqueous solution. Thallium tarnishes readily in moist air and reacts with steam to form TlOH. It is readily soluble in acids, particularly HNO3, and is highly toxic. As a result of its toxicity, thallium is rarely used, with the exception of the manufacture of special grades of glass. In the past, thallium compounds found applications as diverse as rat poisons and hair restorers!

   

Atomic Properties

Atomic number 81
Atomic radius - Goldschmidt ( nm ) 0.171
Atomic weight ( amu ) 204.383
Crystal structure Hexagonal close packed
Electronic structure Xe 4f14 5d1O 6s2 6p1
Ionization potential No. eV
1 6.11
2 20.4
3 29.8
4 50.7
Natural isotope distribution Mass No. %
203 29.5
205 70.5
Photo-electric work function ( eV ) 3.8
Thermal neutron absorption cross-section ( Barns ) 3.4
Valences shown 1, 3

Electrical Properties

Electrical resistivity @20C ( µOhmcm ) 16.6
Temperature coefficient @0-100C ( K-1 ) 0.0052
Superconductivity critical temperature ( K ) 2.38
Thermal emf against Pt (cold 0C - hot 100C) ( mV ) +0.58

Mechanical Properties

Material condition Polycrystalline
Bulk modulus ( GPa ) 28.5
Hardness - Brinell 2.0
Poisson's ratio 0.45
Tensile modulus ( GPa ) 7.9
Tensile strength ( MPa ) 8.96

Physical Properties

Boiling point ( C ) 1457
Density @20C ( g cm-3 ) 11.85
Melting point ( C ) 303.5

Thermal Properties

Coefficient of thermal expansion @0-100C ( x10-6 K-1 ) 30.0
Latent heat of evaporation ( J g-1 ) 813
Latent heat of fusion ( J g-1 ) 21.0
Specific heat @25C ( J K-1 kg-1 ) 128
Thermal conductivity @0-100C ( W m-1 K-1 ) 46.1

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